| http://purl.uniprot.org/citations/15361623 | http://www.w3.org/1999/02/22-rdf-syntax-ns#type | http://purl.uniprot.org/core/Journal_Citation |
| http://purl.uniprot.org/citations/15361623 | http://www.w3.org/1999/02/22-rdf-syntax-ns#type | http://purl.uniprot.org/core/Journal_Citation |
| http://purl.uniprot.org/citations/15361623 | http://www.w3.org/2000/01/rdf-schema#comment | "Siderophores are extracellular iron-binding compounds that mediate iron transport into many cells. We present evidence of analogous molecules for copper transport from methane-oxidizing bacteria, represented here by a small fluorescent chromopeptide (C45N12O14H62Cu, 1216 daltons) produced by Methylosinus trichosporium OB3b. The crystal structure of this compound, methanobactin, was resolved to 1.15 angstroms. It is composed of a tetrapeptide, a tripeptide, and several unusual moieties, including two 4-thionyl-5-hydroxy-imidazole chromophores that coordinate the copper, a pyrrolidine that confers a bend in the overall chain, and an amino-terminal isopropylester group. The copper coordination environment includes a dual nitrogen- and sulfur-donating system derived from the thionyl imidazolate moieties. Structural elucidation of this molecule has broad implications in terms of organo-copper chemistry, biological methane oxidation, and global carbon cycling."xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.org/dc/terms/identifier | "doi:10.1126/science.1098322"xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.org/dc/terms/identifier | "doi:10.1126/science.1098322"xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/author | "Kim H.J."xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/author | "Kim H.J."xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/author | "Alterman M.A."xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/author | "Alterman M.A."xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/author | "Asunskis D."xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/author | "Asunskis D."xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/author | "DiSpirito A.A."xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/author | "DiSpirito A.A."xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/author | "Galeva N."xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/author | "Galeva N."xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/author | "Graham D.W."xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/author | "Graham D.W."xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/author | "Larive C.K."xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/author | "Larive C.K."xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/author | "Sherwood P.M."xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/author | "Sherwood P.M."xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/date | "2004"xsd:gYear |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/date | "2004"xsd:gYear |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/name | "Science"xsd:string |
| http://purl.uniprot.org/citations/15361623 | http://purl.uniprot.org/core/name | "Science"xsd:string |