| http://purl.uniprot.org/citations/16593451 | http://www.w3.org/1999/02/22-rdf-syntax-ns#type | http://purl.uniprot.org/core/Journal_Citation |
| http://purl.uniprot.org/citations/16593451 | http://www.w3.org/1999/02/22-rdf-syntax-ns#type | http://purl.uniprot.org/core/Journal_Citation |
| http://purl.uniprot.org/citations/16593451 | http://www.w3.org/2000/01/rdf-schema#comment | "An extracellular lignin-degrading enzyme from the basidiomycete Phanerochaete chrysosporium Burdsall was purified to homogeneity by ion-exchange chromatography. The 42,000-dalton ligninase contains one protoheme IX per molecule. It catalyzes, nonstereospecifically, several oxidations in the alkyl side chains of lignin-related compounds: C(alpha)-C(beta) cleavage in lignin-related compounds of the type aryl-C(alpha)HOH-C(beta)HR-C(gamma)H(2)OH (R = -aryl or -O-aryl), oxidation of benzyl alcohols to aldehydes or ketones, intradiol cleavage in phenylglycol structures, and hydroxylation of benzylic methylene groups. It also catalyzes oxidative coupling of phenols, perhaps explaining the long-recognized association between phenol oxidation and lignin degradation. All reactions require H(2)O(2). The C(alpha)-C(beta) cleavage and methylene hydroxylation reactions involve substrate oxygenation; the oxygen atom is from O(2) and not H(2)O(2). Thus the enzyme is an oxygenase, unique in its requirement for H(2)O(2)."xsd:string |
| http://purl.uniprot.org/citations/16593451 | http://purl.org/dc/terms/identifier | "doi:10.1073/pnas.81.8.2280"xsd:string |
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| http://purl.uniprot.org/citations/16593451 | http://purl.uniprot.org/core/author | "Kirk T.K."xsd:string |
| http://purl.uniprot.org/citations/16593451 | http://purl.uniprot.org/core/author | "Kirk T.K."xsd:string |
| http://purl.uniprot.org/citations/16593451 | http://purl.uniprot.org/core/author | "Tien M."xsd:string |
| http://purl.uniprot.org/citations/16593451 | http://purl.uniprot.org/core/author | "Tien M."xsd:string |
| http://purl.uniprot.org/citations/16593451 | http://purl.uniprot.org/core/date | "1984"xsd:gYear |
| http://purl.uniprot.org/citations/16593451 | http://purl.uniprot.org/core/date | "1984"xsd:gYear |
| http://purl.uniprot.org/citations/16593451 | http://purl.uniprot.org/core/name | "Proc. Natl. Acad. Sci. U.S.A."xsd:string |
| http://purl.uniprot.org/citations/16593451 | http://purl.uniprot.org/core/name | "Proc. Natl. Acad. Sci. U.S.A."xsd:string |
| http://purl.uniprot.org/citations/16593451 | http://purl.uniprot.org/core/pages | "2280-2284"xsd:string |
| http://purl.uniprot.org/citations/16593451 | http://purl.uniprot.org/core/pages | "2280-2284"xsd:string |
| http://purl.uniprot.org/citations/16593451 | http://purl.uniprot.org/core/title | "Lignin-degrading enzyme from Phanerochaete chrysosporium: purification, characterization, and catalytic properties of a unique H2O2-requiring oxygenase."xsd:string |
| http://purl.uniprot.org/citations/16593451 | http://purl.uniprot.org/core/title | "Lignin-degrading enzyme from Phanerochaete chrysosporium: purification, characterization, and catalytic properties of a unique H2O2-requiring oxygenase."xsd:string |
| http://purl.uniprot.org/citations/16593451 | http://purl.uniprot.org/core/volume | "81"xsd:string |
| http://purl.uniprot.org/citations/16593451 | http://purl.uniprot.org/core/volume | "81"xsd:string |
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| http://purl.uniprot.org/citations/16593451 | http://www.w3.org/2004/02/skos/core#exactMatch | http://purl.uniprot.org/pubmed/16593451 |
| http://purl.uniprot.org/citations/16593451 | http://xmlns.com/foaf/0.1/primaryTopicOf | https://pubmed.ncbi.nlm.nih.gov/16593451 |
| http://purl.uniprot.org/citations/16593451 | http://xmlns.com/foaf/0.1/primaryTopicOf | https://pubmed.ncbi.nlm.nih.gov/16593451 |
| http://purl.uniprot.org/uniprot/P06181 | http://purl.uniprot.org/core/citation | http://purl.uniprot.org/citations/16593451 |
| http://purl.uniprot.org/uniprot/P06181#attribution-43215B6E2875842608A010086673AD2F | http://purl.uniprot.org/core/source | http://purl.uniprot.org/citations/16593451 |