| http://purl.uniprot.org/citations/17444707 | http://www.w3.org/1999/02/22-rdf-syntax-ns#type | http://purl.uniprot.org/core/Journal_Citation |
| http://purl.uniprot.org/citations/17444707 | http://www.w3.org/2000/01/rdf-schema#comment | "The photodissociation of 2-propyl leading to propene+H was investigated with nanosecond time resolution. A supersonic beam of isolated 2-propyl radicals was produced by pyrolysis of 2-bromopopane. The kinetic energy release of the H-atom photofragment was monitored as a function of excitation wavelength by photofragment Doppler spectroscopy via the Lyman-alpha transition. The loss of hydrogen atoms after excitation proceeds in alpha position to the radical center with a rate constant of 5.8x10(7) s-1 at 254 nm. Approximately 20% of the excess energy is deposited as translation in the H-atom photofragment. In contrast 1-propyl does not lose H atoms to a significant extent. The experimental results are compared to simple Rice-Ramsperger-Kassel-Marcus calculations. The possible reaction pathways are examined in hybrid density functional theory calculations."xsd:string |
| http://purl.uniprot.org/citations/17444707 | http://purl.org/dc/terms/identifier | "doi:10.1063/1.2715917"xsd:string |
| http://purl.uniprot.org/citations/17444707 | http://purl.uniprot.org/core/author | "Fischer I."xsd:string |
| http://purl.uniprot.org/citations/17444707 | http://purl.uniprot.org/core/author | "Noller B."xsd:string |
| http://purl.uniprot.org/citations/17444707 | http://purl.uniprot.org/core/date | "2007"xsd:gYear |
| http://purl.uniprot.org/citations/17444707 | http://purl.uniprot.org/core/name | "J Chem Phys"xsd:string |
| http://purl.uniprot.org/citations/17444707 | http://purl.uniprot.org/core/pages | "144302"xsd:string |
| http://purl.uniprot.org/citations/17444707 | http://purl.uniprot.org/core/title | "Photodissociation dynamics of the 2-propyl radical, C3H7."xsd:string |
| http://purl.uniprot.org/citations/17444707 | http://purl.uniprot.org/core/volume | "126"xsd:string |
| http://purl.uniprot.org/citations/17444707 | http://www.w3.org/2004/02/skos/core#exactMatch | http://purl.uniprot.org/pubmed/17444707 |
| http://purl.uniprot.org/citations/17444707 | http://xmlns.com/foaf/0.1/primaryTopicOf | https://pubmed.ncbi.nlm.nih.gov/17444707 |
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| http://purl.uniprot.org/uniprot/#_Q657B3-mappedCitation-17444707 | http://www.w3.org/1999/02/22-rdf-syntax-ns#object | http://purl.uniprot.org/citations/17444707 |
| http://purl.uniprot.org/uniprot/Q657B3 | http://purl.uniprot.org/core/mappedCitation | http://purl.uniprot.org/citations/17444707 |
| http://purl.uniprot.org/uniprot/A0A0P0V4B6 | http://purl.uniprot.org/core/mappedCitation | http://purl.uniprot.org/citations/17444707 |