| http://purl.uniprot.org/citations/19763315 | http://www.w3.org/1999/02/22-rdf-syntax-ns#type | http://purl.uniprot.org/core/Journal_Citation |
| http://purl.uniprot.org/citations/19763315 | http://www.w3.org/1999/02/22-rdf-syntax-ns#type | http://purl.uniprot.org/core/Journal_Citation |
| http://purl.uniprot.org/citations/19763315 | http://www.w3.org/1999/02/22-rdf-syntax-ns#type | http://purl.uniprot.org/core/Citation |
| http://purl.uniprot.org/citations/19763315 | http://www.w3.org/2000/01/rdf-schema#comment | "Verruculogen is a tremorgenic mycotoxin and contains an endoperoxide bond. In this study, we describe the cloning, overexpression and purification of a non-heme Fe(ii) and alpha-ketoglutarate-dependent dioxygenase FtmOx1 from Aspergillus fumigatus, which catalyses the conversion of fumitremorgin B to verruculogen by inserting an endoperoxide bond between two prenyl moieties. Incubation with (18)O(2)-enriched atmosphere demonstrated that both oxygen atoms of the endoperoxide bond are derived from one molecule of O(2). FtmOx1 is the first endoperoxide-forming non-heme Fe(ii) and alpha-ketoglutarate-dependent dioxygenase reported so far. A mechanism of FtmOx1-catalysed verruculogen formation is postulated and discussed."xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.org/dc/terms/identifier | "doi:10.1039/b908392h"xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.org/dc/terms/identifier | "doi:10.1039/b908392h"xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/author | "Grundmann A."xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/author | "Grundmann A."xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/author | "Li S.M."xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/author | "Li S.M."xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/author | "Steffan N."xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/author | "Steffan N."xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/author | "Afiyatullov S."xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/author | "Afiyatullov S."xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/author | "Ruan H."xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/author | "Ruan H."xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/date | "2009"xsd:gYear |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/date | "2009"xsd:gYear |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/name | "Org. Biomol. Chem."xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/name | "Org. Biomol. Chem."xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/pages | "4082-4087"xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/pages | "4082-4087"xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/title | "FtmOx1, a non-heme Fe(II) and alpha-ketoglutarate-dependent dioxygenase, catalyses the endoperoxide formation of verruculogen in Aspergillus fumigatus."xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/title | "FtmOx1, a non-heme Fe(II) and alpha-ketoglutarate-dependent dioxygenase, catalyses the endoperoxide formation of verruculogen in Aspergillus fumigatus."xsd:string |
| http://purl.uniprot.org/citations/19763315 | http://purl.uniprot.org/core/volume | "7"xsd:string |