| http://purl.uniprot.org/citations/26274339 | http://www.w3.org/1999/02/22-rdf-syntax-ns#type | http://purl.uniprot.org/core/Journal_Citation |
| http://purl.uniprot.org/citations/26274339 | http://www.w3.org/1999/02/22-rdf-syntax-ns#type | http://purl.uniprot.org/core/Journal_Citation |
| http://purl.uniprot.org/citations/26274339 | http://www.w3.org/2000/01/rdf-schema#comment | "The sesquiterpenoid 7-epi-neopetasone was synthesized via the Wieland-Miescher ketone. The compound was identical to a previously tentatively identified headspace constituent of Penicillium roqueforti. Feeding experiments with (13) C-labeled mevalonolactone isotopomers demonstrated that oxidation at C12 and an isomerization of the C11C12 to a C7C11 double bond must occur independently and not via a C7-C11-C12 allyl radical in one step. Feeding with (11,12,13-(13) C3 )-7-epi-neopetasone resulted in labelling of the PR toxin, thus establishing this compound as a newly identified pathway intermediate."xsd:string |
| http://purl.uniprot.org/citations/26274339 | http://purl.org/dc/terms/identifier | "doi:10.1002/anie.201506128"xsd:string |
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| http://purl.uniprot.org/citations/26274339 | http://purl.uniprot.org/core/author | "Dickschat J.S."xsd:string |
| http://purl.uniprot.org/citations/26274339 | http://purl.uniprot.org/core/author | "Dickschat J.S."xsd:string |
| http://purl.uniprot.org/citations/26274339 | http://purl.uniprot.org/core/author | "Riclea R."xsd:string |
| http://purl.uniprot.org/citations/26274339 | http://purl.uniprot.org/core/author | "Riclea R."xsd:string |
| http://purl.uniprot.org/citations/26274339 | http://purl.uniprot.org/core/date | "2015"xsd:gYear |
| http://purl.uniprot.org/citations/26274339 | http://purl.uniprot.org/core/date | "2015"xsd:gYear |
| http://purl.uniprot.org/citations/26274339 | http://purl.uniprot.org/core/name | "Angew. Chem. Int. Ed."xsd:string |
| http://purl.uniprot.org/citations/26274339 | http://purl.uniprot.org/core/name | "Angew. Chem. Int. Ed."xsd:string |
| http://purl.uniprot.org/citations/26274339 | http://purl.uniprot.org/core/pages | "12167-12170"xsd:string |
| http://purl.uniprot.org/citations/26274339 | http://purl.uniprot.org/core/pages | "12167-12170"xsd:string |
| http://purl.uniprot.org/citations/26274339 | http://purl.uniprot.org/core/title | "Identification of intermediates in the biosynthesis of PR toxin by Penicillium roqueforti."xsd:string |
| http://purl.uniprot.org/citations/26274339 | http://purl.uniprot.org/core/title | "Identification of intermediates in the biosynthesis of PR toxin by Penicillium roqueforti."xsd:string |
| http://purl.uniprot.org/citations/26274339 | http://purl.uniprot.org/core/volume | "54"xsd:string |
| http://purl.uniprot.org/citations/26274339 | http://purl.uniprot.org/core/volume | "54"xsd:string |
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