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http://purl.uniprot.org/citations/28718766http://www.w3.org/1999/02/22-rdf-syntax-ns#typehttp://purl.uniprot.org/core/Journal_Citation
http://purl.uniprot.org/citations/28718766http://www.w3.org/2000/01/rdf-schema#comment"In plants, algae and cyanobacteria, Photosystem II (PSII) catalyzes the light-driven splitting of water at a protein-bound Mn4CaO5-cluster, the water-oxidizing complex (WOC). In the photosynthetic organisms, the light-driven formation of the WOC from dissolved metal ions is a key process because it is essential in both initial activation and continuous repair of PSII. Structural information is required for understanding of this chaperone-free metal-cluster assembly. For the first time, we obtained a structure of PSII from Thermosynechococcus elongatus without the Mn4CaO5-cluster. Surprisingly, cluster-removal leaves the positions of all coordinating amino acid residues and most nearby water molecules largely unaffected, resulting in a pre-organized ligand shell for kinetically competent and error-free photo-assembly of the Mn4CaO5-cluster. First experiments initiating (i) partial disassembly and (ii) partial re-assembly after complete depletion of the Mn4CaO5-cluster agree with a specific bi-manganese cluster, likely a di-µ-oxo bridged pair of Mn(III) ions, as an assembly intermediate."xsd:string
http://purl.uniprot.org/citations/28718766http://purl.org/dc/terms/identifier"doi:10.7554/elife.26933"xsd:string
http://purl.uniprot.org/citations/28718766http://purl.uniprot.org/core/author"Zhang M."xsd:string
http://purl.uniprot.org/citations/28718766http://purl.uniprot.org/core/author"Bommer M."xsd:string
http://purl.uniprot.org/citations/28718766http://purl.uniprot.org/core/author"Dobbek H."xsd:string
http://purl.uniprot.org/citations/28718766http://purl.uniprot.org/core/author"Kern J."xsd:string
http://purl.uniprot.org/citations/28718766http://purl.uniprot.org/core/author"Zouni A."xsd:string
http://purl.uniprot.org/citations/28718766http://purl.uniprot.org/core/author"Dau H."xsd:string
http://purl.uniprot.org/citations/28718766http://purl.uniprot.org/core/author"Yano J."xsd:string
http://purl.uniprot.org/citations/28718766http://purl.uniprot.org/core/author"Chatterjee R."xsd:string
http://purl.uniprot.org/citations/28718766http://purl.uniprot.org/core/author"Hussein R."xsd:string
http://purl.uniprot.org/citations/28718766http://purl.uniprot.org/core/date"2017"xsd:gYear
http://purl.uniprot.org/citations/28718766http://purl.uniprot.org/core/name"Elife"xsd:string
http://purl.uniprot.org/citations/28718766http://purl.uniprot.org/core/pages"e26933"xsd:string
http://purl.uniprot.org/citations/28718766http://purl.uniprot.org/core/title"Structural insights into the light-driven auto-assembly process of the water-oxidizing Mn4CaO5-cluster in photosystem II."xsd:string
http://purl.uniprot.org/citations/28718766http://purl.uniprot.org/core/volume"6"xsd:string
http://purl.uniprot.org/citations/28718766http://www.w3.org/2004/02/skos/core#exactMatchhttp://purl.uniprot.org/pubmed/28718766
http://purl.uniprot.org/citations/28718766http://xmlns.com/foaf/0.1/primaryTopicOfhttps://pubmed.ncbi.nlm.nih.gov/28718766
http://purl.uniprot.org/uniprot/#_P59087-mappedCitation-28718766http://www.w3.org/1999/02/22-rdf-syntax-ns#objecthttp://purl.uniprot.org/citations/28718766
http://purl.uniprot.org/uniprot/#_P0A386-mappedCitation-28718766http://www.w3.org/1999/02/22-rdf-syntax-ns#objecthttp://purl.uniprot.org/citations/28718766
http://purl.uniprot.org/uniprot/#_P0A431-mappedCitation-28718766http://www.w3.org/1999/02/22-rdf-syntax-ns#objecthttp://purl.uniprot.org/citations/28718766
http://purl.uniprot.org/uniprot/#_P0A444-mappedCitation-28718766http://www.w3.org/1999/02/22-rdf-syntax-ns#objecthttp://purl.uniprot.org/citations/28718766
http://purl.uniprot.org/uniprot/#_Q9F1K9-mappedCitation-28718766http://www.w3.org/1999/02/22-rdf-syntax-ns#objecthttp://purl.uniprot.org/citations/28718766
http://purl.uniprot.org/uniprot/#_Q9F1L5-mappedCitation-28718766http://www.w3.org/1999/02/22-rdf-syntax-ns#objecthttp://purl.uniprot.org/citations/28718766