http://purl.uniprot.org/citations/7039616 | http://www.w3.org/1999/02/22-rdf-syntax-ns#type | http://purl.uniprot.org/core/Journal_Citation |
http://purl.uniprot.org/citations/7039616 | http://www.w3.org/2000/01/rdf-schema#comment | "Adenosine 5'[gamma(S)-16O, 17O, 18O]triphosphate has been synthesized and used to determine the stereochemical course of phosphoryl transfer catalysed by yeast hexokinase. The chirality at phosphorus of the D-glucose 6-[16O,17O,18O]phosphate formed was analysed, after cyclization and methylation, by 31P n.m.r. spectroscopy. The phosphoryl transfer was found to occur with inversion of configuration, with a stereoselectivity in excess of 94%. The simplest interpretation of this result is that the phosphoryl group is transferred between substrates in the enzyme-substrate ternary complex by an 'in line' mechanism."xsd:string |
http://purl.uniprot.org/citations/7039616 | http://purl.org/dc/terms/identifier | "doi:10.1042/bj1990227"xsd:string |
http://purl.uniprot.org/citations/7039616 | http://purl.uniprot.org/core/author | "Lowe G."xsd:string |
http://purl.uniprot.org/citations/7039616 | http://purl.uniprot.org/core/author | "Potter B.V."xsd:string |
http://purl.uniprot.org/citations/7039616 | http://purl.uniprot.org/core/date | "1981"xsd:gYear |
http://purl.uniprot.org/citations/7039616 | http://purl.uniprot.org/core/name | "Biochem J"xsd:string |
http://purl.uniprot.org/citations/7039616 | http://purl.uniprot.org/core/pages | "227-233"xsd:string |
http://purl.uniprot.org/citations/7039616 | http://purl.uniprot.org/core/title | "The stereochemical course of yeast hexokinase-catalysed phosphoryl transfer by using adenosine 5'[gamma(S)-16O,17O,18O]triphosphate as substrate."xsd:string |
http://purl.uniprot.org/citations/7039616 | http://purl.uniprot.org/core/volume | "199"xsd:string |
http://purl.uniprot.org/citations/7039616 | http://www.w3.org/2004/02/skos/core#exactMatch | http://purl.uniprot.org/pubmed/7039616 |
http://purl.uniprot.org/citations/7039616 | http://xmlns.com/foaf/0.1/primaryTopicOf | https://pubmed.ncbi.nlm.nih.gov/7039616 |
http://purl.uniprot.org/uniprot/#_P04806-mappedCitation-7039616 | http://www.w3.org/1999/02/22-rdf-syntax-ns#object | http://purl.uniprot.org/citations/7039616 |
http://purl.uniprot.org/uniprot/#_P04807-mappedCitation-7039616 | http://www.w3.org/1999/02/22-rdf-syntax-ns#object | http://purl.uniprot.org/citations/7039616 |
http://purl.uniprot.org/uniprot/P04807 | http://purl.uniprot.org/core/mappedCitation | http://purl.uniprot.org/citations/7039616 |
http://purl.uniprot.org/uniprot/P04806 | http://purl.uniprot.org/core/mappedCitation | http://purl.uniprot.org/citations/7039616 |